A strategy toward the synthesis of C13-oxidized cembrenolides
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چکیده
منابع مشابه
A strategy toward the synthesis of C13-oxidized cembrenolides.
An efficient strategy for the construction of C13-oxidized cembrenolides is reported. Central to this strategy is the installation of the C13 hydroxyl group prior to cembrane macrocyclization (via formation of the C1-C2 bond), allowing access to both C13 alcohol epimers. The orientation of the C13 alcohol was found to influence the cyclization mode of the cembranolide scaffold upon furan oxidat...
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A Fischer Indolization Strategy toward the Total Synthesis of (-)-goniomitine.
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ژورنال
عنوان ژورنال: Tetrahedron Letters
سال: 2013
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2013.01.085